Falcelinta vulkanization ee peroxide sare -kulka silikoonka caagga ah ee vulkanized wuxuu ku socdaa iyadoo loo eegayo habka falcelinta xagjirka ee xorta ah. Xaaladaha kulaylinta, peroxides organic ayaa u jajaban si ay u soo saaraan xagjirro bilaash ah, ka dibna la falgala kooxaha organic ee ku jira molecules polysiloxane sida methyl iyo kooxaha ethyl si ay u sameeyaan xagjirayaal bilaash ah oo sarreeya. Marka kuwan sare - xagjiryada xorta ah ee molecular lamaanan yihiin midba midka kale, -isku xidhiddu waa dhacdaa.
Waxa jira lix peroxides oo si caadi ah loo isticmaalo oo ku jira caag silikoon ah oo heerkulkiisu sarreeyo- Xaaladaha vulkanization iyo baaxadda lagu dabaqi karo ee peroxides organic kala duwan ma aha isku mid.
Isticmaalayaashu waxay dooran karaan isku-dhafka ku habboon hadba baahidooda. Tusaale ahaan, heerkulka hoose - kala furfurida kulaylka peroxides sida di peroxide (2, 4-dichlorobenzene) waxay ku siin kartaa heer aad u degdeg ah vulcanization, iyo cadaadiska uumiga ee xeryahooda qudhmay aad buu u hooseeyaa, markaa looma baahna cadaadis dheeraad ah si looga hortago samaynta daldaloolada. Sidaa darteed, xaruntan waxaa badanaa loo isticmaalaa hawada kulul ee vulcanization extrusion iyo hababka qaabeynta. Si kastaba ha ahaatee, xawaaraha vulcanization-ka oo aad u dheereeya awgeed, xawaaladuhu waxay u nugul yihiin inay dhacaan marka la tuurayo alaabada khafiifka ah ama la wareejinayo caaryada. Xaaladahan oo kale, peroxides leh xawaare vulcanization ah, sida benzoyl peroxide, ayaa ku habboon.
Si kastaba ha ahaatee, xaruntani waxay soo saari doontaa gaas inta lagu jiro habka vulcanization, markaa laguma soo bandhigi karo hawo kulul. Taa beddelkeeda, vulkanization joogto ah oo leh uumi ayaa caadi ahaan la isticmaalaa. Cilad kale oo kuwan sare ah-ee hoosaysa-Wakiilada heerkulku waa in marka la tuurayo badeecooyinka khafiifka ah, alaabtooda qudhmisa aashitada ay saamayn taban ku yeelan doonto xasiloonida kulaylka ee alaabta.
In kasta oo - wakiilada heerkulku sareeyo sida diisopropylbenzene peroxide iyo di-tert{2}butyl peroxide ay ku haboon yihiin oo kaliya caag cayriin methyl vinyl aadka u falceliya, waa wakiilada vulcanizing ugu fiican ee alaabta qaro weyn waxaana sidoo kale loo isticmaali karaa kaarboon madow{3}}